April 2026 • 2026AJ....171..227L
Abstract • WD 0806 b is a rare exoplanet companion orbiting a white dwarf, currently with a projected orbital distance of 2500 au. The Spitzer mid-IR photometry suggests that the temperature is as cold as 350 K, making it one of the coldest directly imaged exoplanets. In this paper, we present the Near-infrared Camera (NIRCam) F150W2, F200W, F356W, and F444W broadband photometry and a 3─5 μm Near-Infrared spectroscopy (NIRSpec) G395M spectrum obtained with the James Webb Space Telescope. We develop a new retrieval framework based on the open-source PICASO software that includes additive and multiplicative systematic parameters. Our retrieval results reveal bounded abundances of H2S, CO2, CO, NH3, H2O, and CH4. We present a new chemical analysis framework that utilizes retrieved abundances to measure altitude-dependent eddy diffusion coefficients (Kzz) at multiple quenched pressures. We find that the eddy diffusion coefficients decrease from around 104─102 cm2 s−1 as the atmospheric pressure decreases from from 50 to 20 bar. To our knowledge, this is the first study to report altitude-dependent vertical mixing (or, equivalently, quenched-species-dependent vertical mixing) based on the measured molecular abundances of CO, CH4, and CO2. With the 1─21 μm NIRCam, NIRSpec, and the previously published MIRI data, we measure the bolometric luminosity to be log(L/L⊙) = −6.75 ± 0.01 and derive the mass to be 8 ± 1MJ. The retrieval results suggest that WD 0806 b has an elevated C/O ratio of 0.76, or 1.3× solar, subsolar metallicity ([M/H ]= −0.25), and a nearly solar C/S ratio (1.17x solar).
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