Herschel Space Observatory - Theoretical Research Proposal #1018 THz Time Domain Spectroscopy of Astrophysical Dust Analogs, Ices, and Complex Organics Principal Investigator: Geoffrey Blake Institution: Caltech Dollars Approved: 175000 Abstract: Photons at far-infrared (far-IR)/TeraHertz (THz) frequencies hold the keys to many of the outstanding issues in astrophysics. To fully realize the promise of Herschel, however, it is essential that we achieve a quantitative experimental understanding of the far-IR properties of the dust, ice, and gas which make up the ISM; yet THz laboratory studies largely lag behind the astronomical capabilities that Herschel will deploy, thanks primarily to technological limitations. Here we propose to use femtosecond THz Time Domain Spectroscopy (THz TDS) to acquire high dynamic range optical constants of the major components that comprise astrophysical dust and ice across the full wavelength region accessible to Herschel and over temperatures from 7-300 K. We also propose to study the lowest frequency skeletal vibrations of PAHs and the torsions of complex organics such as glycine in both the solid state and gas phase in order to permit Herschel studies of prebiotic chemical evolution.